Information Society's What's on Your Mind (Pure Energy) is from one of the first CDs I ever bought.
Leiahdorus' Indigent was also an album from my freshman year. I remember singing it on my way to class.
A few other songs from long ago that were also fitting included
New Order's Every Little Counts and Alphaville's Forever Young
Overall I am really impressed with the songs last.fm is adding to the radio database. Echo Image and Leiahdorus are not bands I ever expected to hear on last.fm